Proportional Error In Chemistry
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while others can not. The ultimate result of these uncertainties is that the true value of a measurement can NEVER be known exactly! Precision Refers to the reproducibility of measurements or the closeness of results measured in exactly proportional error definition the same way. In other words, it is the grouping of data. Accuracy Is
Proportional Error Formula
the closeness of the measurement to its true or accepted value. Mean Median The middle value when replicate data are arranged in
Error In Chemical Analysis
order of size. For an odd number of data it is the middle value. For and even number of data it is the average of the middle two values Range (v) The difference between the
Types Of Errors In Analytical Chemistry Ppt
highest value and the lowest value Deviation from the mean (d) or arithmetic deviation The absolute value of the difference between the measured value and the mean. It is the magnitude of the deviation. Relative Arithmetic Deviation (dR) Difference between the measured value and the mean compared to the mean. Standard deviation (S,s)
Must consider the number of data and the degrees of freedom. Sample standard deviation (<20 measurements) Population errors in chemical analysis pdf standard deviation (>20 measurements) Variance (s2, s2) Square of the standard deviation. Relative standard deviation (RSD) The standard deviation compared to the mean. Absolute error The difference between the measured value and the true value. It has a sign (+/-). Relative error The absolute error divided by the true value. It has a has a sign (+/-) Click on icon for power point presentation (LAN). Click on icon for power point presentation (internet). Systemic Errors Systematic errors can come from several sources. They can be classified as instrument errors, method errors and personal errors. Instrument errors are due to imperfections in measuring devices and instabilities in power supplies. They can be detected and minimized by calibrating the instrument. Method errors are caused by non-ideal chemical or physical behaviors. These may include: Slowness of reactions Instability of certain species Nonspecificity of most reagents Possible occurrence of side reactions Method errors can be detected by using the following techniques: Analysis of standard reference materials (SRMs) Independent analysis Blank determinations (performing all steps of an analysis in the absence of sample) Variation in sample size (identifies constant errors) Personal errors can be due to personal bias and prejudice and physical limitations and handicaps. Personal erEngineering Medicine Agriculture Photosciences Humanities Periodic Table of the Elements Reference Tables Physical Constants Units and Conversions Organic Chemistry Glossary Search site Search Search Go back to types of errors in analytical method previous article Username Password Sign in Sign in Sign in Registration Forgot difference between absolute and relative error password Expand/collapse global hierarchy Home Textbook Maps Analytical Chemistry Textbook Maps Map: Analytical Chemistry 2.0 (Harvey) 4: Evaluating method error in chemistry Analytical Data Expand/collapse global location 4.2: Characterizing Experimental Errors Last updated 13:21, 26 May 2016 Save as PDF Share Share Share Tweet Share 4.2.1 Errors Affecting AccuracySampling ErrorsMethod ErrorsMeasurement ErrorsPersonal ErrorsIdentifying http://www.chemtech.org/cn/cn206/206-2.htm Determinate Errors4.2.2 Errors Affecting PrecisionSources of Indeterminate ErrorEvaluating Indeterminate Error4.2.3 Error and UncertaintyContributors Characterizing the mass of a penny using the data in Table 4.1 suggests two questions. First, does our measure of central tendency agree with the penny’s expected mass? Second, why is there so much variability in the individual results? The first of these questions addresses the accuracy of our http://chem.libretexts.org/Textbook_Maps/Analytical_Chemistry_Textbook_Maps/Map%3A_Analytical_Chemistry_2.0_(Harvey)/04_Evaluating_Analytical_Data/4.2%3A_Characterizing_Experimental_Errors measurements, and the second asks about their precision. In this section we consider the types of experimental errors affecting accuracy and precision. 4.2.1 Errors Affecting Accuracy Accuracy is a measure of how close a measure of central tendency is to the expected value, μ. We can express accuracy as either an absolute error, e \[e = \overline{X} - μ\tag{4.2}\] or as a percent relative error, %er. \[\%e_\ce{r}= \dfrac{\overline{X} − μ}{μ} × 100\tag{4.3}\] Note The convention for representing statistical parameters is to use a Roman letter for a value calculated from experimental data, and a Greek letter for the corresponding expected value. For example, the experimentally determined mean is X, and its underlying expected value is ì. Likewise, the standard deviation by experiment is s, and the underlying expected value is s. Although equations 4.2 and 4.3 use the mean as the measure of central tendency, we also can use the median. We call errors affecting the accuracy of an analysis determinate. Although there may be several different sources of determinate error, each source has a specific magnitude and sign. Some sources of dete
Engineering Medicine Agriculture Photosciences Humanities Periodic Table of the Elements Reference Tables Physical Constants Units and Conversions http://chem.libretexts.org/Core/Analytical_Chemistry/Quantifying_Nature/Significant_Digits/Uncertainties_in_Measurements Organic Chemistry Glossary Search site Search Search Go back to previous article Username Password Sign in Sign in Sign in Registration Forgot password Expand/collapse global hierarchy Home Core Analytical Chemistry Quantifying Nature Expand/collapse global location Uncertainties in Measurements Last updated 11:37, 3 Sep 2015 Save as PDF Share Share Share Tweet proportional error Share IntroductionSystematic vs. Random ErrorA Graphical RepresentationPrecision vs. AccuracyCalculating ErrorMethods of Reducing ErrorReferencesProblemsSolutions All measurements have a degree of uncertainty regardless of precision and accuracy. This is caused by two factors, the limitation of the measuring instrument (systematic error) and the skill of the experimenter making the measurements (random error). Introduction The error in chemistry graduated buret in Figure 1 contains a certain amount of water (with yellow dye) to be measured. The amount of water is somewhere between 19 ml and 20 ml according to the marked lines. By checking to see where the bottom of the meniscus lies, referencing the ten smaller lines, the amount of water lies between 19.8 ml and 20 ml. The next step is to estimate the uncertainty between 19.8 ml and 20 ml. Making an approximate guess, the level is less than 20 ml, but greater than 19.8 ml. We then report that the measured amount is approximately 19.9 ml. The graduated cylinder itself may be distorted such that the graduation marks contain inaccuracies providing readings slightly different from the actual volume of liquid present. Figure 1: A meniscus as seen in a burette of colored water. '20.00 mL' is the correct depth measurement. Click here for a more