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Proportional Error In Chemistry

while others can not. The ultimate result of these uncertainties is that the true value of a measurement can NEVER be known exactly! Precision Refers to the reproducibility of measurements or the closeness of results measured in exactly the same way. In

Proportional Error Definition

other words, it is the grouping of data. Accuracy Is the closeness of the proportional error formula measurement to its true or accepted value. Mean Median The middle value when replicate data are arranged in order of size. For error in chemical analysis an odd number of data it is the middle value. For and even number of data it is the average of the middle two values Range (v) The difference between the highest value and the lowest value

Types Of Errors In Analytical Chemistry Ppt

Deviation from the mean (d) or arithmetic deviation The absolute value of the difference between the measured value and the mean. It is the magnitude of the deviation. Relative Arithmetic Deviation (dR) Difference between the measured value and the mean compared to the mean. Standard deviation (S,s)

Must consider the number of data and the degrees of freedom. Sample standard deviation (<20 measurements) Population standard deviation (>20 measurements) Variance (s2, s2) Square of

Errors In Chemical Analysis Pdf

the standard deviation.

Relative standard deviation (RSD) The standard deviation compared to the mean. Absolute error The difference between the measured value and the true value. It has a sign (+/-). Relative error The absolute error divided by the true value. It has a has a sign (+/-) Click on icon for power point presentation (LAN). Click on icon for power point presentation (internet). Systemic Errors Systematic errors can come from several sources. They can be classified as instrument errors, method errors and personal errors. Instrument errors are due to imperfections in measuring devices and instabilities in power supplies. They can be detected and minimized by calibrating the instrument. Method errors are caused by non-ideal chemical or physical behaviors. These may include: Slowness of reactions Instability of certain species Nonspecificity of most reagents Possible occurrence of side reactions Method errors can be detected by using the following techniques: Analysis of standard reference materials (SRMs) Independent analysis Blank determinations (performing all steps of an analysis in the absence of sample) Variation in sample size (identifies constant errors) Personal errors can be due to personal bias and prejudice and physical limitations and handicaps. Personal errors can be minimized through personal discipline and training. Systematic errors can also be classified as either proportional errors or

Toys Science & Nature Science Difference Between Constant & Proportional Error Difference Between Constant & Proportional Error By William Rockwell eHow Contributor William Rockwell Follow  types of errors in analytical method Pin  Share  Tweet Share  Email Save Understanding the difference between

Difference Between Absolute And Relative Error

constant and proportional error in statistical analysis will allow a function to be properly graphed. Once a graph method error in chemistry is completed any value on the y axis can be found if the x value is known and vice versa. Constant Error A constant error is an average of the errors http://www.chemtech.org/cn/cn206/206-2.htm over the range of all data. The x value will be independent of the y value. For example, an affixed scale will always have deviation from the zero setting whether the item being weighed is 100 lbs., 600 lbs. or anywhere in between and this error has nothing to do with the actual weight of the object. The average deviation of http://www.ehow.com/info_12185218_difference-between-constant-proportional-error.html a single instance will decrease as the number of instances increases. Proportional Error Proportional error is an error that is dependent on the amount of change in a specific variable. So the change in x is directly related to the change in y. This change is always an equally measurable amount so that x divided by y always equals the same constant. The amount of error will always be a consistent percentage. Indeterminate Error An indeterminate error is one that is neither constant or proportional. These errors are often the result of observer bias or inconsistent methodology during an experiment. Indeterminate errors can also be a sign that there is absolutely no correlation between the two items being compared. In cases like this it is important to revisit all facets of data collection including experimental bias and inconsistent measurements. Graphing A constant error will be reflected in a change in the y intercept on the graph. A proportional error will change the slope of the line on the graph. Indeterminate errors will cause a scatter plot effect on the graph, making the determination

Engineering Medicine Agriculture Photosciences Humanities Periodic Table of the Elements Reference Tables Physical Constants Units and Conversions Organic Chemistry Glossary Search site Search Search Go back to previous http://chem.libretexts.org/Core/Analytical_Chemistry/Quantifying_Nature/Significant_Digits/Uncertainties_in_Measurements article Username Password Sign in Sign in Sign in Registration Forgot password Expand/collapse global hierarchy Home Core Analytical Chemistry Quantifying Nature Expand/collapse global location Uncertainties in Measurements Last updated 11:37, 3 Sep 2015 Save as PDF Share Share Share Tweet Share IntroductionSystematic vs. Random ErrorA Graphical RepresentationPrecision vs. AccuracyCalculating ErrorMethods of Reducing ErrorReferencesProblemsSolutions All measurements have a degree of uncertainty regardless of proportional error precision and accuracy. This is caused by two factors, the limitation of the measuring instrument (systematic error) and the skill of the experimenter making the measurements (random error). Introduction The graduated buret in Figure 1 contains a certain amount of water (with yellow dye) to be measured. The amount of water is somewhere between 19 ml and 20 ml according to the marked error in chemistry lines. By checking to see where the bottom of the meniscus lies, referencing the ten smaller lines, the amount of water lies between 19.8 ml and 20 ml. The next step is to estimate the uncertainty between 19.8 ml and 20 ml. Making an approximate guess, the level is less than 20 ml, but greater than 19.8 ml. We then report that the measured amount is approximately 19.9 ml. The graduated cylinder itself may be distorted such that the graduation marks contain inaccuracies providing readings slightly different from the actual volume of liquid present. Figure 1: A meniscus as seen in a burette of colored water. '20.00 mL' is the correct depth measurement. Click here for a more complete description on buret use, including proper reading. Figure used with permission from Wikipedia. Systematic vs. Random Error The diagram below illustrates the distinction between systematic and random errors. Figure 2: Systematic and random errors. Figure used with permission from David DiBiase (Penn State U). Systematic errors: When we use tools meant for measurement, we assume that they are correct and accurate, however measuring tools are n

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