Calculating Systematic Error Chemistry
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of the measurement device. Random errors usually result from the experimenter's inability to take the same measurement in exactly
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the same way to get exact the same number. Systematic how to calculate systematic error in excel errors, by contrast, are reproducible inaccuracies that are consistently in the same direction. Systematic errors are
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often due to a problem which persists throughout the entire experiment. Note that systematic and random errors refer to problems associated with making measurements. Mistakes made examples of systematic error in chemistry in the calculations or in reading the instrument are not considered in error analysis. It is assumed that the experimenters are careful and competent! How to minimize experimental error: some examples Type of Error Example How to minimize it Random errors You measure the mass of a ring three times using the same calculating statistical error balance and get slightly different values: 17.46 g, 17.42 g, 17.44 g Take more data. Random errors can be evaluated through statistical analysis and can be reduced by averaging over a large number of observations. Systematic errors The cloth tape measure that you use to measure the length of an object had been stretched out from years of use. (As a result, all of your length measurements were too small.)The electronic scale you use reads 0.05 g too high for all your mass measurements (because it is improperly tared throughout your experiment). Systematic errors are difficult to detect and cannot be analyzed statistically, because all of the data is off in the same direction (either to high or too low). Spotting and correcting for systematic error takes a lot of care. How would you compensate for the incorrect results of using the stretched out tape measure? How would you correct the measurements from improperly tared scale?
Treatments MSDS Resources Applets General FAQ Uncertainty ChemLab Home Computing Uncertainties in Laboratory Data and Result This section considers the error and uncertainty in experimental
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measurements and calculated results. First, here are some fundamental things systematic error formula you should realize about uncertainty: • Every measurement has an uncertainty associated with it, unless it is
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an exact, counted integer, such as the number of trials performed. • Every calculated result also has an uncertainty, related to the uncertainty in the measured data https://www2.southeastern.edu/Academics/Faculty/rallain/plab193/labinfo/Error_Analysis/05_Random_vs_Systematic.html used to calculate it. This uncertainty should be reported either as an explicit ± value or as an implicit uncertainty, by using the appropriate number of significant figures. • The numerical value of a "plus or minus" (±) uncertainty value tells you the range of the result. For example a result reported as 1.23 ± https://www.dartmouth.edu/~chemlab/info/resources/uncertain.html 0.05 means that the experimenter has some degree of confidence that the true value falls in between 1.18 and 1.28. • When significant figures are used as an implicit way of indicating uncertainty, the last digit is considered uncertain. For example, a result reported as 1.23 implies a minimum uncertainty of ±0.01 and a range of 1.22 to 1.24. • For the purposes of General Chemistry lab, uncertainty values should only have one significant figure. It generally doesn't make sense to state an uncertainty any more precisely. To consider error and uncertainty in more detail, we begin with definitions of accuracy and precision. Then we will consider the types of errors possible in raw data, estimating the precision of raw data, and three different methods to determine the uncertainty in calculated results. Accuracy and Precision The accuracy of a set of observations is the difference between the average of the measured values and the true value of the observed quantity. The
Slideshare uses cookies to improve functionality and performance, and to provide you with relevant advertising. If you continue browsing http://www.slideshare.net/wkkok1957/ib-chemistry-on-uncertainty-error-calculation-random-and-systematic-error-precision-and-accuracy-9468016 the site, you agree to the use of cookies on this http://chem.libretexts.org/Core/Analytical_Chemistry/Quantifying_Nature/Significant_Digits/Uncertainties_in_Measurements website. See our Privacy Policy and User Agreement for details. SlideShare Explore Search You Upload Login Signup Home Technology Education More Topics For Uploaders Get Started Tips & Tricks Tools IB Chemistry on uncertainty error calculation, random and systematic error, precision and accuracy Upcoming SlideShare systematic error Loading in …5 × 1 1 of 7 Like this document? Why not share! Share Email IB Chemistry, IB Biology on Uncerta... byLawrence kok 46880views IB Chemistry, IB Biology on Uncerta... byLawrence kok 33050views Video tutorial on how to add standa... byLawrence kok 27239views Uncertainty and equipment error byChris Paine 53408views Physics 1.2b Errors systematic error in and Uncertainties byJohnPaul Kennedy 93966views IB Chemistry on Uncertainty, Error ... byLawrence kok 6822views Share SlideShare Facebook Twitter LinkedIn Google+ Email Email sent successfully! Embed Size (px) Start on Show related SlideShares at end WordPress Shortcode Link IB Chemistry on uncertainty error calculation, random and systematic error, precision and accuracy 65,950 views Share Like Download Lawrence kok, HS IB Science teacher Follow 0 0 1 Published on Sep 29, 2011 IB Chemistry on uncertainty error calculation, random and systematic error, precision and accuracy ... Published in: Education, Technology License: CC Attribution-NonCommercial-ShareAlike License 0 Comments 3 Likes Statistics Notes Full Name Comment goes here. 12 hours ago Delete Reply Spam Block Are you sure you want to Yes No Your message goes here Post Be the first to comment Rejectedxpokemon 11 months ago Ma HA 1 year ago mrsangirasa 2 years ago No Downloads Views Total views 65,950 On SlideShare 0 From Embeds 0 Number of Embeds 21,808 Actions Shares 0 Downloads 381 Comments
Engineering Medicine Agriculture Photosciences Humanities Periodic Table of the Elements Reference Tables Physical Constants Units and Conversions Organic Chemistry Glossary Search site Search Search Go back to previous article Username Password Sign in Sign in Sign in Registration Forgot password Expand/collapse global hierarchy Home Core Analytical Chemistry Quantifying Nature Expand/collapse global location Uncertainties in Measurements Last updated 11:37, 3 Sep 2015 Save as PDF Share Share Share Tweet Share IntroductionSystematic vs. Random ErrorA Graphical RepresentationPrecision vs. AccuracyCalculating ErrorMethods of Reducing ErrorReferencesProblemsSolutions All measurements have a degree of uncertainty regardless of precision and accuracy. This is caused by two factors, the limitation of the measuring instrument (systematic error) and the skill of the experimenter making the measurements (random error). Introduction The graduated buret in Figure 1 contains a certain amount of water (with yellow dye) to be measured. The amount of water is somewhere between 19 ml and 20 ml according to the marked lines. By checking to see where the bottom of the meniscus lies, referencing the ten smaller lines, the amount of water lies between 19.8 ml and 20 ml. The next step is to estimate the uncertainty between 19.8 ml and 20 ml. Making an approximate guess, the level is less than 20 ml, but greater than 19.8 ml. We then report that the measured amount is approximately 19.9 ml. The graduated cylinder itself may be distorted such that the graduation marks contain inaccuracies providing readings slightly different from the actual volume of liquid present. Figure 1: A meniscus as seen in a burette of colored water. '20.00 mL' is the correct depth measurement. Click here for a more complete description on buret use, including proper reading. Figure used with permission from Wikipedia. Systematic vs. Random Error The diagram below illustrates the distinction between systematic and random errors. Figure 2: Systematic and random errors. Figure used with permission from David DiBiase (Penn State U). Systematic errors: When we use tools meant for measurement, we assume that they are correct and accurate, however measuring tools are not always right. In fact, they have errors that naturally occur called systematic errors. Systematic errors tend to be consistent in magnitude and/or directio