Error Propagation Rules Chemistry
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Engineering Medicine Agriculture Photosciences Humanities Periodic Table of the Elements Reference Tables Physical Constants Units and Conversions Organic Chemistry Glossary Search site Search Search error propagation analytical chemistry Go back to previous article Username Password Sign in Sign in error propagation rules exponents Sign in Registration Forgot password Expand/collapse global hierarchy Home Core Analytical Chemistry Quantifying Nature Expand/collapse global location Propagation error propagation rules division of Error Last updated 20:33, 14 May 2016 Save as PDF Share Share Share Tweet Share IntroductionDerivation of Exact FormulaDerivation of Arithmetic ExampleCaveats and WarningsDisadvantages of Propagation of Error
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ApproachTreatment of Covariance TermsReferencesContributors Propagation of Error (or Propagation of Uncertainty) is defined as the effects on a function by a variable's uncertainty. It is a calculus derived statistical calculation designed to combine uncertainties from multiple variables, in order to provide an accurate measurement of uncertainty. Introduction Every measurement has an air of uncertainty about it, and not all how to do error propagation uncertainties are equal. Therefore, the ability to properly combine uncertainties from different measurements is crucial. Uncertainty in measurement comes about in a variety of ways: instrument variability, different observers, sample differences, time of day, etc. Typically, error is given by the standard deviation (\(\sigma_x\)) of a measurement. Anytime a calculation requires more than one variable to solve, propagation of error is necessary to properly determine the uncertainty. For example, lets say we are using a UV-Vis Spectrophotometer to determine the molar absorptivity of a molecule via Beer's Law: A = ε l c. Since at least two of the variables have an uncertainty based on the equipment used, a propagation of error formula must be applied to measure a more exact uncertainty of the molar absorptivity. This example will be continued below, after the derivation (see Example Calculation). Derivation of Exact Formula Suppose a certain experiment requires multiple instruments to carry out. These instruments each have different variability in their measurements. The results of each instrument are given as: a, b, c, d... (Fo
or more quantities, each with their individual uncertainties, and then combine the information from these quantities in order to come up with a final result of our experiment. How can you state your answer for the combined result of these measurements and their uncertainties scientifically? The answer to this fairly error propagation formula common question depends on how the individual measurements are combined in the result. We will treat
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each case separately: Addition of measured quantities If you have measured values for the quantities X, Y, and Z, with uncertainties dX, dY, and
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dZ, and your final result, R, is the sum or difference of these quantities, then the uncertainty dR is: Here the upper equation is an approximation that can also serve as an upper bound for the error. Please note that http://chem.libretexts.org/Core/Analytical_Chemistry/Quantifying_Nature/Significant_Digits/Propagation_of_Error the rule is the same for addition and subtraction of quantities. Example: Suppose we have measured the starting position as x1 = 9.3+-0.2 m and the finishing position as x2 = 14.4+-0.3 m. Then the displacement is: Dx = x2-x1 = 14.4 m - 9.3 m = 5.1 m and the error in the displacement is: (0.22 + 0.32)1/2 m = 0.36 m Multiplication of measured quantities In the same way as for sums and differences, we can also state the http://lectureonline.cl.msu.edu/~mmp/labs/error/e2.htm result for the case of multiplication and division: Again the upper line is an approximation and the lower line is the exact result for independent random uncertainties in the individual variables. And again please note that for the purpose of error calculation there is no difference between multiplication and division. Example: We have measured a displacement of x = 5.1+-0.4 m during a time of t = 0.4+-0.1 s. What is the average velocity and the error in the average velocity? v = x / t = 5.1 m / 0.4 s = 12.75 m/s and the uncertainty in the velocity is: dv = |v| [ (dx/x)2 + (dt/t)2 ]1/2 = 12.75 m/s [(0.4/5.1)2 + (0.1/0.4)2]1/2 = 3.34 m/s Multiplication with a constant What if you have measured the uncertainty in an observable X, and you need to multiply it with a constant that is known exactly? What is the error then? This is easy: just multiply the error in X with the absolute value of the constant, and this will give you the error in R: If you compare this to the above rule for multiplication of two quantities, you see that this is just the special case of that rule for the uncertainty in c, dc = 0. Example: If an object is realeased from rest and is in free fall, and if you measure the velocity of this object at some point to be v =
Laboratory Laboratory Safety Glassware and Equipment Instrumentation Data Analysis Laboratory Reports Assessment Installing LoggerPro Course-Specific Information Chemistry for Contemporary Living Chemical Principles http://chemlab.truman.edu/DataAnalysis/Propagation%20of%20Error/PropagationofError.asp Inorganic Chemistry Instrumental Analysis Organic Chemistry Physical Chemistry Quantitative Analysis Undergraduate http://www.chem.hope.edu/~polik/Chem345-2000/errorpropagation.htm research Chemistry of Art (JINS) Help Chemistry Contact Center AXE Tutoring Review Guides Proofreader's marks Forms Crystal Model Request Form Liq. Nitrogen Request Form NMR Class Submission Form Databases and References AIST Spectral Database NIST WebBook NMR Solvents ChemLab.Truman Home» Propagation of Uncertainty error propagation Author: J. M. McCormick Last Update: August 27, 2010 Introduction Every measurement that we make in the laboratory has some degree of uncertainty associated with it simply because no measuring device is perfect. If a desired quantity can be found directly from a single measurement, then the uncertainty in the quantity is completely determined error propagation rules by the precision of the measurement. It is not so simple, however, when a quantity must be calculated from two or more measurements, each with their own uncertainty. In this case the precision of the final result depends on the uncertainties in each of the measurements that went into calculating it. In other words, uncertainty is always present and a measurement’s uncertainty is always carried through all calculations that use it. Fundamental Equations One might think that all we need to do is perform the calculation at the extreme of each variable’s confidence interval, and the result reflecting the uncertainty in the calculated quantity. Although this works in some instances, it usually fails, because we need to account for the distribution of possible values in all of the measured variables and how that affects the distribution of values in the calculated quantity. Although this seems like a daunting task, the problem is solvable, and it has been solved, but t
x, y, or z leads to an error in the determination of u. This is simply the multi-dimensional definition of slope. It describes how changes in u depend on changes in x, y, and z. Example: A miscalibrated ruler results in a systematic error in length measurements. The values of r and h must be changed by +0.1 cm. 3. Random Errors Random errors in the measurement of x, y, or z also lead to error in the determination of u. However, since random errors can be both positive and negative, one should examine (du)2 rather than du. If the measured variables are independent (non-correlated), then the cross-terms average to zero as dx, dy, and dz each take on both positive and negative values. Thus, Equating standard deviation with differential, i.e., results in the famous error propagation formula This expression will be used in the Uncertainty Analysis section of every Physical Chemistry laboratory report! Example: There is 0.1 cm uncertainty in the ruler used to measure r and h. Thus, the expected uncertainty in V is ±39 cm3. 4. Purpose of Error Propagation · Quantifies precision of results Example: V = 1131 ± 39 cm3 · Identifies principle source of error and suggests improvement Example: Determine r better (not h!) · Justifies observed standard deviation If sobserved » scalculated then the observed standard deviation is accounted for If sobserved differs significantly from scalculated then perhaps unrealistic values were chosen for sx, sy, and sz. · Identifies type of error If ½uobserrved - uliterature½ £ scalculated then error is random error If ½uobserrved - uliterature½ >> scalculated then error is systematic error 5. Calculating and Reporting Values when using Error Propagation Use full precision (keep extra significant figures and do not round) until the end of a calculation. Then keep two significant