Error Propegation
Contents |
or more quantities, each with their individual uncertainties, and then combine the information from these quantities in order to come up with a final result of our experiment. How can you state your answer for the combined result of these measurements and their error propagation calculator uncertainties scientifically? The answer to this fairly common question depends on how the individual measurements error propagation example are combined in the result. We will treat each case separately: Addition of measured quantities If you have measured values for the error propagation formula quantities X, Y, and Z, with uncertainties dX, dY, and dZ, and your final result, R, is the sum or difference of these quantities, then the uncertainty dR is: Here the upper equation is an approximation error propagation physics that can also serve as an upper bound for the error. Please note that the rule is the same for addition and subtraction of quantities. Example: Suppose we have measured the starting position as x1 = 9.3+-0.2 m and the finishing position as x2 = 14.4+-0.3 m. Then the displacement is: Dx = x2-x1 = 14.4 m - 9.3 m = 5.1 m and the error in the displacement is: (0.22 + 0.32)1/2 m
Error Propagation Chemistry
= 0.36 m Multiplication of measured quantities In the same way as for sums and differences, we can also state the result for the case of multiplication and division: Again the upper line is an approximation and the lower line is the exact result for independent random uncertainties in the individual variables. And again please note that for the purpose of error calculation there is no difference between multiplication and division. Example: We have measured a displacement of x = 5.1+-0.4 m during a time of t = 0.4+-0.1 s. What is the average velocity and the error in the average velocity? v = x / t = 5.1 m / 0.4 s = 12.75 m/s and the uncertainty in the velocity is: dv = |v| [ (dx/x)2 + (dt/t)2 ]1/2 = 12.75 m/s [(0.4/5.1)2 + (0.1/0.4)2]1/2 = 3.34 m/s Multiplication with a constant What if you have measured the uncertainty in an observable X, and you need to multiply it with a constant that is known exactly? What is the error then? This is easy: just multiply the error in X with the absolute value of the constant, and this will give you the error in R: If you compare this to the above rule for multiplication of two quantities, you see that this is just the sp
Engineering Medicine Agriculture Photosciences Humanities Periodic Table of the Elements Reference Tables Physical Constants Units and Conversions Organic Chemistry Glossary Search site Search Search Go back
Error Propagation Calculus
to previous article Username Password Sign in Sign in Sign in Registration Forgot error propagation addition password Expand/collapse global hierarchy Home Core Analytical Chemistry Quantifying Nature Expand/collapse global location Propagation of Error Last updated error analysis propagation 20:33, 14 May 2016 Save as PDF Share Share Share Tweet Share IntroductionDerivation of Exact FormulaDerivation of Arithmetic ExampleCaveats and WarningsDisadvantages of Propagation of Error ApproachTreatment of Covariance TermsReferencesContributors Propagation of http://lectureonline.cl.msu.edu/~mmp/labs/error/e2.htm Error (or Propagation of Uncertainty) is defined as the effects on a function by a variable's uncertainty. It is a calculus derived statistical calculation designed to combine uncertainties from multiple variables, in order to provide an accurate measurement of uncertainty. Introduction Every measurement has an air of uncertainty about it, and not all uncertainties are equal. Therefore, the ability to properly http://chem.libretexts.org/Core/Analytical_Chemistry/Quantifying_Nature/Significant_Digits/Propagation_of_Error combine uncertainties from different measurements is crucial. Uncertainty in measurement comes about in a variety of ways: instrument variability, different observers, sample differences, time of day, etc. Typically, error is given by the standard deviation (\(\sigma_x\)) of a measurement. Anytime a calculation requires more than one variable to solve, propagation of error is necessary to properly determine the uncertainty. For example, lets say we are using a UV-Vis Spectrophotometer to determine the molar absorptivity of a molecule via Beer's Law: A = ε l c. Since at least two of the variables have an uncertainty based on the equipment used, a propagation of error formula must be applied to measure a more exact uncertainty of the molar absorptivity. This example will be continued below, after the derivation (see Example Calculation). Derivation of Exact Formula Suppose a certain experiment requires multiple instruments to carry out. These instruments each have different variability in their measurements. The results of each instrument are given as: a, b, c, d... (For simplification purposes, only the variables a, b, and c will be used throughout this derivation). The en
Random Entry New in MathWorld MathWorld Classroom About MathWorld Contribute to MathWorld Send a Message to the Team MathWorld Book Wolfram Web Resources» 13,594 entries Last updated: Tue Sep 27 2016 Created, developed, and http://mathworld.wolfram.com/ErrorPropagation.html nurturedbyEricWeisstein at WolframResearch Probability and Statistics>Error Analysis> Interactive Entries>Interactive Demonstrations> Error Propagation Given a formula with an absolute error in of , the absolute error is . The relative error https://www.lhup.edu/~dsimanek/scenario/errorman/rules.htm is . If , then (1) where denotes the mean, so the sample variance is given by (2) (3) The definitions of variance and covariance then give (4) (5) error propagation (6) (where ), so (7) If and are uncorrelated, then so (8) Now consider addition of quantities with errors. For , and , so (9) For division of quantities with , and , so (10) Dividing through by and rearranging then gives (11) For exponentiation of quantities with (12) and (13) so (14) (15) If , then (16) For logarithms error propagation calculator of quantities with , , so (17) (18) For multiplication with , and , so (19) (20) (21) For powers, with , , so (22) (23) SEE ALSO: Absolute Error, Accuracy, Covariance, Percentage Error, Precision, Relative Error, Significant Digits, Variance REFERENCES: Abramowitz, M. and Stegun, I.A. (Eds.). Handbook of Mathematical Functions with Formulas, Graphs, and Mathematical Tables, 9th printing. New York: Dover, p.14, 1972. Bevington, P.R. Data Reduction and Error Analysis for the Physical Sciences. New York: McGraw-Hill, pp.58-64, 1969. Referenced on Wolfram|Alpha: Error Propagation CITE THIS AS: Weisstein, Eric W. "Error Propagation." From MathWorld--A Wolfram Web Resource. http://mathworld.wolfram.com/ErrorPropagation.html Wolfram Web Resources Mathematica» The #1 tool for creating Demonstrations and anything technical. Wolfram|Alpha» Explore anything with the first computational knowledge engine. Wolfram Demonstrations Project» Explore thousands of free applications across science, mathematics, engineering, technology, business, art, finance, social sciences, and more. Computerbasedmath.org» Join the initiative for modernizing math education. Online Integral Calculator» Solve integrals with Wolfram|Alpha. Step-by-step Solutions» Walk through homework problems step-by-step from beginning to end. Hints help you try the next step on your own. Wo
constant size. Indeterminate errors have unpredictable size and sign, with equal likelihood of being + or -. RULES FOR ELEMENTARY OPERATIONS (DETERMINATE ERRORS) SUM RULE: When R = A + B then ΔR = ΔA + ΔB DIFFERENCE RULE: When R = A - B then ΔR = ΔA - ΔB PRODUCT RULE: When R = AB then (ΔR)/R = (ΔA)/A + (ΔB)/B QUOTIENT RULE: When R = A/B then (ΔR)/R = (ΔA)/A + (ΔB)/B POWER RULE: When R = An then (ΔR)/R = n(ΔA)/A or (ΔR) = n An-1(ΔA) Memory clues: When quantities are added (or subtracted) their absolute errors add (or subtract). But when quantities are multiplied (or divided), their relative fractional errors add (or subtract). These rules will be freely used, when appropriate. We can also collect and tabulate the results for commonly used elementary functions. Note: Where Δt appears, it must be expressed in radians. RULES FOR ELEMENTARY FUNCTIONS (DETERMINATE ERRORS) EQUATION ERROR EQUATION R = sin q ΔR = (dq) cos q R = cos q ΔR = -(dq) sin q R = tan q ΔR = (dq) sec2 q R = ex ΔR = (Δx) ex R = e-x ΔR = -(Δx) e-x R = ln(x) ΔR = (Δx)/x Any measures of error may be converted to relative (fractional) form by using the definition of relative error. The fractional error in x is: fx = (ΔR)x)/x where (ΔR)x is the absolute ereror in x. Therefore xfx = (ΔR)x. The rules for indeterminate errors are simpler. RULES FOR ELEMENTARY OPERATIONS (INDETERMINATE ERRORS) SUM OR DIFFERENCE: When R = A + B then ΔR = ΔA + ΔB PRODUCT OR QUOTIENT: When R = AB then (ΔR)/R = (ΔA)/A + (ΔB)/B POWER RULE: When R = An then (ΔR)/R = n(ΔA)/A or (ΔR) = n An-1(ΔA) The indeterminate error rules for elementary functions are the same as those for determinate errors except that the error terms on the right are all positive. Students who are takin