Multivariate Propagation Of Error Formula
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Error Propagation Physics
IntroductionDerivation of Exact FormulaDerivation of Arithmetic ExampleCaveats and WarningsDisadvantages of Propagation of Error ApproachTreatment of Covariance TermsReferencesContributors Propagation of Error (or Propagation of Uncertainty) is defined as the effects on a function by a variable's
Error Propagation Chemistry
uncertainty. It is a calculus derived statistical calculation designed to combine uncertainties from multiple variables, in order to provide an accurate measurement of uncertainty. Introduction Every measurement has an air of uncertainty about it, and not all uncertainties are equal. Therefore, the ability to properly combine uncertainties from different measurements is crucial. Uncertainty in measurement comes about in a variety of ways: instrument variability, different observers, sample differences, time error propagation square root of day, etc. Typically, error is given by the standard deviation (\(\sigma_x\)) of a measurement. Anytime a calculation requires more than one variable to solve, propagation of error is necessary to properly determine the uncertainty. For example, lets say we are using a UV-Vis Spectrophotometer to determine the molar absorptivity of a molecule via Beer's Law: A = ε l c. Since at least two of the variables have an uncertainty based on the equipment used, a propagation of error formula must be applied to measure a more exact uncertainty of the molar absorptivity. This example will be continued below, after the derivation (see Example Calculation). Derivation of Exact Formula Suppose a certain experiment requires multiple instruments to carry out. These instruments each have different variability in their measurements. The results of each instrument are given as: a, b, c, d... (For simplification purposes, only the variables a, b, and c will be used throughout this derivation). The end result desired is \(x\), so that \(x\) is dependent on a, b, and c. It can be written that \(x\) is a function of these variables: \[x=f(a,b,c) \tag{1}\] Because each measurement has an uncertainty about its mean, it can be written that the uncertainty of dxi of t
The approach to uncertainty analysis that has been followed up to this point in the discussion has been what is called a top-down approach. Uncertainty components are estimated from direct repetitions of the measurement result. To contrast this with
Error Propagation Reciprocal
a propagation of error approach, consider the simple example where we estimate the error propagation excel area of a rectangle from replicate measurements of length and width. The area $$ area = length \cdot width error propagation inverse $$ can be computed from each replicate. The standard deviation of the reported area is estimated directly from the replicates of area. Advantages of top-down approach This approach has the following advantages: proper http://chem.libretexts.org/Core/Analytical_Chemistry/Quantifying_Nature/Significant_Digits/Propagation_of_Error treatment of covariances between measurements of length and width proper treatment of unsuspected sources of error that would emerge if measurements covered a range of operating conditions and a sufficiently long time period independence from propagation of error model Propagation of error approach combines estimates from individual auxiliary measurements The formal propagation of error approach is to compute: standard deviation from the length measurements standard deviation http://www.itl.nist.gov/div898/handbook/mpc/section5/mpc55.htm from the width measurements and combine the two into a standard deviation for area using the approximation for products of two variables (ignoring a possible covariance between length and width), $$ s_{area} = \sqrt{width^2 \cdot s_{length}^2 + length^2 \cdot s_{width}^2} $$ Exact formula Goodman (1960) derived an exact formula for the variance between two products. Given two random variables, \(x\) and \(y\) (correspond to width and length in the above approximate formula), the exact formula for the variance is: $$ V(\bar{x} \bar{y}) = \frac{1}{n} \left[ X^2 V(y) + Y^2 V(x) + 2XYE_{11} + 2X\frac{E_{12}}{n} + 2Y\frac{E_{21}}{n} + \frac{V(x) V(y)}{n} + \frac{Cov((\Delta x)^2, (\Delta y)^2) -E_{11}^2 }{n^2} \right] $$ with \(X = E(x)\) and \(Y = E(y)\) (corresponds to width and length, respectively, in the approximate formula) \(V(x)\) is the variance of \(x\) and \(V(y)\) is the variance \(y\) (corresponds to \(s^2\) for width and length, respectively, in the approximate formula) \( E_{ij} = {(\Delta x)^i, (\Delta y)^j}\) where \( \Delta x = x - X \) and \( \Delta y = y - Y \) \( Cov((\Delta x)^2, (\Delta y)^2) = E_{22} - V(x) V(y) \) To obtain the standard deviation, simply take the
Engineering Medicine Agriculture Photosciences Humanities Periodic Table of the Elements Reference Tables Physical Constants Units http://chem.libretexts.org/Core/Analytical_Chemistry/Quantifying_Nature/Significant_Digits/Propagation_of_Error and Conversions Organic Chemistry Glossary Search site Search Search Go https://www.lhup.edu/~dsimanek/scenario/errorman/calculus.htm back to previous article Username Password Sign in Sign in Sign in Registration Forgot password Expand/collapse global hierarchy Home Core Analytical Chemistry Quantifying Nature Expand/collapse global location Propagation of Error Last updated 20:33, 14 May 2016 Save as PDF Share Share error propagation Share Tweet Share IntroductionDerivation of Exact FormulaDerivation of Arithmetic ExampleCaveats and WarningsDisadvantages of Propagation of Error ApproachTreatment of Covariance TermsReferencesContributors Propagation of Error (or Propagation of Uncertainty) is defined as the effects on a function by a variable's uncertainty. It is a calculus derived statistical calculation designed to combine uncertainties multivariate propagation of from multiple variables, in order to provide an accurate measurement of uncertainty. Introduction Every measurement has an air of uncertainty about it, and not all uncertainties are equal. Therefore, the ability to properly combine uncertainties from different measurements is crucial. Uncertainty in measurement comes about in a variety of ways: instrument variability, different observers, sample differences, time of day, etc. Typically, error is given by the standard deviation (\(\sigma_x\)) of a measurement. Anytime a calculation requires more than one variable to solve, propagation of error is necessary to properly determine the uncertainty. For example, lets say we are using a UV-Vis Spectrophotometer to determine the molar absorptivity of a molecule via Beer's Law: A = ε l c. Since at least two of the variables have an uncertainty based on the equipment used, a propagation of error formula must be applied to measure a more exact uncertainty of the mol
with: (1) Functions of several variables. (2) Evaluation of partial derivatives, and the chain rules of differentiation. (3) Manipulation of summations in algebraic context. At this mathematical level our presentation can be briefer. We can dispense with the tedious explanations and elaborations of previous chapters. 6.2 THE CHAIN RULE AND DETERMINATE ERRORS If a result R = R(x,y,z) is calculated from a number of data quantities, x, y and z, then the relation: [6-1] ∂R ∂R ∂R dR = —— dx + —— dy + —— dz ∂x ∂y ∂z
holds. This is one of the "chain rules" of calculus. This equation has as many terms as there are variables. Then, if the fractional errors are small, the differentials dR, dx, dy and dz may be replaced by the absolute errors ΔR, Δx, Δy, and Δz, and written: [6-2] ∂R ∂R ∂R ΔR ≈ —— Δx + —— Δy + —— Δz ∂x ∂y ∂z Strictly this is no longer an equality, but an approximation to DR, since the higher order terms in the Taylor expansion have been neglected. So long as the errors are of the order of a few percent or less, this will not matter. This equation is now an error propagation equation. [6-3] Finally, divide equation (6.2) by R: ΔR x ∂R Δx y ∂R Δy z ∂R Δz —— = —————+——— ——+————— R R ∂x x R ∂y y R ∂z z The factors of the form Δx/x, Δy/y, etc are relative (fractional) errors. This equation shows how the errors in the result depend on the errors in the data. Eq. 6.2 and 6.3 are called the standard form error equations. They are also called determinate error equations, because they are strictly valid for determinate errors (not indeterminate errors). [We'll get to indeterminate errors soon.] The coefficients in Eq. 6.3 of the fractional errors are of the form [(x/R)(∂R/dx)]. These play the very important role of "weighting" factors in the various error terms. At this point numeric values of the relative errors could be substituted into this equation, along with the other measured quantities, x, y, z, to calculate ΔR. Notice the character of the standard form error equation. It has one t