Notes On The Use Of Propagation Of Error Formulas
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site Search Search Go back to previous article Username Password Sign in Sign in Sign in Registration Forgot password Expand/collapse global hierarchy Home Core Analytical Chemistry Quantifying Nature Expand/collapse global location Propagation of Error Last updated 20:33, 14 May 2016 Save as PDF Share Share Share Tweet Share IntroductionDerivation of Exact FormulaDerivation of Arithmetic ExampleCaveats and WarningsDisadvantages https://archive.org/stream/jresv70Cn4p263/jresv70Cn4p263_A1b_djvu.txt of Propagation of Error ApproachTreatment of Covariance TermsReferencesContributors Propagation of Error (or Propagation of Uncertainty) is defined as the effects on a function by a variable's uncertainty. It is a calculus derived statistical calculation designed to combine uncertainties from multiple variables, in order to provide an accurate measurement of uncertainty. Introduction Every measurement has an air http://chem.libretexts.org/Core/Analytical_Chemistry/Quantifying_Nature/Significant_Digits/Propagation_of_Error of uncertainty about it, and not all uncertainties are equal. Therefore, the ability to properly combine uncertainties from different measurements is crucial. Uncertainty in measurement comes about in a variety of ways: instrument variability, different observers, sample differences, time of day, etc. Typically, error is given by the standard deviation (\(\sigma_x\)) of a measurement. Anytime a calculation requires more than one variable to solve, propagation of error is necessary to properly determine the uncertainty. For example, lets say we are using a UV-Vis Spectrophotometer to determine the molar absorptivity of a molecule via Beer's Law: A = ε l c. Since at least two of the variables have an uncertainty based on the equipment used, a propagation of error formula must be applied to measure a more exact uncertainty of the molar absorptivity. This example will be continued below, after the derivation (see Example Calculation). Derivation of Exact Formula Suppose a certain experiment requires multiple instruments to carry out. These instruments each have different variability in their measur
from GoogleSign inHidden fieldsBooksbooks.google.comhttps://books.google.com/books/about/Precision_Measurement_and_Calibration_St.html?id=-_ZQAAAAMAAJ&utm_source=gb-gplus-sharePrecision Measurement and Calibration: Statistical concepts and procedures, H. H. Ku, edMy libraryHelpAdvanced Book SearchDownload PDFeBook - FREEGet https://books.google.com/books?id=-_ZQAAAAMAAJ&pg=PA435&lpg=PA435&dq=notes+on+the+use+of+propagation+of+error+formulas&source=bl&ots=G9ca2FZ6Cm&sig=d1SG7mmnu6Q1v4R3AqgrJH2gvlE&hl=en&sa=X&ved=0ahUKEwiiu6Tk7-PPAhUBWmMKHXi this book in printAbeBooksOn Demand BooksAmazonFind in a libraryAll sellers»Precision Measurement and Calibration: Statistical concepts and procedures, H. H. Ku, edU.S. Government Printing Office, 1961 - Calibration - 513 pages 1 Reviewhttps://books.google.com/books/about/Precision_Measurement_and_Calibration_St.html?id=-_ZQAAAAMAAJ Preview this book » What people are saying-Write a error propagation reviewUser Review - Flag as inappropriateThank you very much. This book is very usefulSelected pagesPage 12Page 7Page 9Page 5Page 3ContentsIntroduction 1 The Measurement Process 2 Process Precision 4 Performance Parameters 5 Designs for Groups of 3 5 or 6 6 Systematic notes on the Errors 7 References 10 Uncertainty Computation 12 Youden W J 131 Functional Relationships 185 Statistical Treatment of Measurement Data 275 Ku Harry H 296 Miscellaneous Topics 355 Abstracts of Recent Publications 409 Surveillance Tests 22 413 Appendix A 11 423 MoreInterpretation of the Uncertainty 13 B ANALYTICAL PROCEDURES 16 The Measurement of Precision and Accuracy 17 APPENDIX 77 Design of Experiments in Calibration 79 Planning the Collaborative Test 424 References 26 432 3 Notes on the use of propagation of error formulas 435 Copyright LessCommon terms and phrasesadjusted analysis applied approximately arithmetic mean ASTM average bias Bureau of Standards calculated calibration Churchill Eisenhart coefficient comparison components computed confidence interval confidence limits constant control chart correct corresponding curve degrees of freedom d