Propagation Of Error Relative Standard Deviation
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Engineering Medicine Agriculture Photosciences Humanities Periodic Table of the Elements Reference Tables Physical Constants Units and Conversions Organic Chemistry Glossary Search site Search Search Go back to previous article Username Password Sign in Sign propagation of error division in Sign in Registration Forgot password Expand/collapse global hierarchy Home Core Analytical Chemistry error propagation calculator Quantifying Nature Expand/collapse global location Propagation of Error Last updated 20:33, 14 May 2016 Save as PDF Share Share Share Tweet error propagation physics Share IntroductionDerivation of Exact FormulaDerivation of Arithmetic ExampleCaveats and WarningsDisadvantages of Propagation of Error ApproachTreatment of Covariance TermsReferencesContributors Propagation of Error (or Propagation of Uncertainty) is defined as the effects on a function by error propagation chemistry a variable's uncertainty. It is a calculus derived statistical calculation designed to combine uncertainties from multiple variables, in order to provide an accurate measurement of uncertainty. Introduction Every measurement has an air of uncertainty about it, and not all uncertainties are equal. Therefore, the ability to properly combine uncertainties from different measurements is crucial. Uncertainty in measurement comes about in a variety of ways: instrument variability, different observers, sample
Error Propagation Excel
differences, time of day, etc. Typically, error is given by the standard deviation (\(\sigma_x\)) of a measurement. Anytime a calculation requires more than one variable to solve, propagation of error is necessary to properly determine the uncertainty. For example, lets say we are using a UV-Vis Spectrophotometer to determine the molar absorptivity of a molecule via Beer's Law: A = ε l c. Since at least two of the variables have an uncertainty based on the equipment used, a propagation of error formula must be applied to measure a more exact uncertainty of the molar absorptivity. This example will be continued below, after the derivation (see Example Calculation). Derivation of Exact Formula Suppose a certain experiment requires multiple instruments to carry out. These instruments each have different variability in their measurements. The results of each instrument are given as: a, b, c, d... (For simplification purposes, only the variables a, b, and c will be used throughout this derivation). The end result desired is \(x\), so that \(x\) is dependent on a, b, and c. It can be written that \(x\) is a function of these variables: \[x=f(a,b,c) \tag{1}\] Because each measurement has an uncertainty about its mean, it can be written that the u
variance is the sum of the individual http://ion.chem.usu.edu/~sbialkow/Classes/3600/Overheads/Propagation/Prop.html variance.
For multiplication and division: In this case error is propagated as the squared relative standard deviation. Other useful formulas are: Back to Chemistry 3600 Home This page was created by Professor Stephen Bialkowski, Utah State University. Tuesday, August 03, 2004"change" in the value of that quantity. Results are is obtained by mathematical operations on the data, and small changes in any data quantity can affect the value of a result. We say that "errors in the https://www.lhup.edu/~dsimanek/scenario/errorman/propagat.htm data propagate through the calculations to produce error in the result." 3.2 MAXIMUM ERROR We first consider how data errors propagate through calculations to affect error limits (or maximum error) of results. It's easiest to first consider determinate errors, which have explicit sign. This leads to useful rules for error propagation. Then we'll modify and extend the rules to other error measures and also to indeterminate errors. The underlying mathematics is that of "finite differences," an algebra for dealing with numbers which error propagation have relatively small variations imposed upon them. The finite differences we are interested in are variations from "true values" caused by experimental errors. Consider a result, R, calculated from the sum of two data quantities A and B. For this discussion we'll use ΔA and ΔB to represent the errors in A and B respectively. The data quantities are written to show the errors explicitly: [3-1] A + ΔA and B + ΔB We allow the possibility that ΔA propagation of error and ΔB may be either positive or negative, the signs being "in" the symbols "ΔA" and "ΔB." The result of adding A and B is expressed by the equation: R = A + B. When errors are explicitly included, it is written: (A + ΔA) + (B + ΔB) = (A + B) + (Δa + δb) So the result, with its error ΔR explicitly shown in the form R + ΔR, is: R + ΔR = (A + B) + (Δa + Δb) [3-2] The error in R is: ΔR = ΔA + ΔB. We conclude that the error in the sum of two quantities is the sum of the errors in those quantities. You can easily work out the case where the result is calculated from the difference of two quantities. In that case the error in the result is the difference in the errors. Summarizing: Sum and difference rule. When two quantities are added (or subtracted), their determinate errors add (or subtract). Now consider multiplication: R = AB. With errors explicitly included: R + ΔR = (A + ΔA)(B + ΔB) = AB + (ΔA)B + A(ΔB) + (ΔA)(ΔB) [3-3] or : ΔR = (ΔA)B + A(ΔB) + (ΔA)(ΔB) This doesn't look like a simple rule. However, when we express the errors in relative form, things look better. When the error a is small relative to A and ΔB is small relative to B, then (ΔA)(ΔB) is certainly small relat
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