Propagation Of Error Using Standard Deviation
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The approach to uncertainty analysis that has been followed up to this point in the discussion has been what is called a top-down approach. Uncertainty components are estimated from direct repetitions of the measurement result. To
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contrast this with a propagation of error approach, consider the simple example error propagation physics where we estimate the area of a rectangle from replicate measurements of length and width. The area $$ area
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= length \cdot width $$ can be computed from each replicate. The standard deviation of the reported area is estimated directly from the replicates of area. Advantages of top-down approach This error propagation definition approach has the following advantages: proper treatment of covariances between measurements of length and width proper treatment of unsuspected sources of error that would emerge if measurements covered a range of operating conditions and a sufficiently long time period independence from propagation of error model Propagation of error approach combines estimates from individual auxiliary measurements The formal propagation of error approach is to error propagation excel compute: standard deviation from the length measurements standard deviation from the width measurements and combine the two into a standard deviation for area using the approximation for products of two variables (ignoring a possible covariance between length and width), $$ s_{area} = \sqrt{width^2 \cdot s_{length}^2 + length^2 \cdot s_{width}^2} $$ Exact formula Goodman (1960) derived an exact formula for the variance between two products. Given two random variables, \(x\) and \(y\) (correspond to width and length in the above approximate formula), the exact formula for the variance is: $$ V(\bar{x} \bar{y}) = \frac{1}{n} \left[ X^2 V(y) + Y^2 V(x) + 2XYE_{11} + 2X\frac{E_{12}}{n} + 2Y\frac{E_{21}}{n} + \frac{V(x) V(y)}{n} + \frac{Cov((\Delta x)^2, (\Delta y)^2) -E_{11}^2 }{n^2} \right] $$ with \(X = E(x)\) and \(Y = E(y)\) (corresponds to width and length, respectively, in the approximate formula) \(V(x)\) is the variance of \(x\) and \(V(y)\) is the variance \(y\) (corresponds to \(s^2\) for width and length, respectively, in the approximate formula) \( E_{ij} = {(\Delta x)^i, (\Delta y)^j}\) where \( \Delta x = x - X \) and \( \Delta y = y - Y \) \( Cov((\Delta x)^2
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Forgot password Expand/collapse global hierarchy Home Core Analytical Chemistry Quantifying Nature Expand/collapse global location Propagation of Error Last updated 20:33, 14 May 2016 Save http://www.itl.nist.gov/div898/handbook/mpc/section5/mpc55.htm as PDF Share Share Share Tweet Share IntroductionDerivation of Exact FormulaDerivation of Arithmetic ExampleCaveats and WarningsDisadvantages of Propagation of Error ApproachTreatment of Covariance TermsReferencesContributors Propagation of Error (or Propagation of Uncertainty) is defined as the effects on a function by a variable's uncertainty. It is a calculus derived statistical http://chem.libretexts.org/Core/Analytical_Chemistry/Quantifying_Nature/Significant_Digits/Propagation_of_Error calculation designed to combine uncertainties from multiple variables, in order to provide an accurate measurement of uncertainty. Introduction Every measurement has an air of uncertainty about it, and not all uncertainties are equal. Therefore, the ability to properly combine uncertainties from different measurements is crucial. Uncertainty in measurement comes about in a variety of ways: instrument variability, different observers, sample differences, time of day, etc. Typically, error is given by the standard deviation (\(\sigma_x\)) of a measurement. Anytime a calculation requires more than one variable to solve, propagation of error is necessary to properly determine the uncertainty. For example, lets say we are using a UV-Vis Spectrophotometer to determine the molar absorptivity of a molecule via Beer's Law: A = ε l c. Since at least two of the variables have an uncertainty based on the equipment used, a propagation of error formula must
Community Forums > Mathematics > Set Theory, Logic, Probability, Statistics > We've just passed 300 Insights! View them here! What a resource! Dismiss Notice Dismiss Notice Join Physics Forums Today! The friendliest, high quality science and math community on the planet! Everyone who loves science is here! Error propagation with averages https://www.physicsforums.com/threads/error-propagation-with-averages-and-standard-deviation.608932/ and standard deviation Page 1 of 2 1 2 Next > May 25, 2012 #1 rano I was http://lectureonline.cl.msu.edu/~mmp/labs/error/e2.htm wondering if someone could please help me understand a simple problem of error propagation going from multiple measurements with errors to an average incorporating these errors. I have looked on several error propagation webpages (e.g. UC physics or UMaryland physics) but have yet to find exactly what I am looking for. I would like to illustrate my question with some example data. Suppose we want to know the mean error propagation ± standard deviation (mean ± SD) of the mass of 3 rocks. We weigh these rocks on a balance and get: Rock 1: 50 g Rock 2: 10 g Rock 3: 5 g So we would say that the mean ± SD of these rocks is: 21.6 ± 24.6 g. But now let's say we weigh each rock 3 times each and now there is some error associated with the mass of each rock. Let's say that the mean ± SD of each rock mass is now: Rock propagation of error 1: 50 ± 2 g Rock 2: 10 ± 1 g Rock 3: 5 ± 1 g How would we describe the mean ± SD of the three rocks now that there is some uncertainty in their masses? Would it still be 21.6 ± 24.6 g? Some error propagation websites suggest that it would be the square root of the sum of the absolute errors squared, divided by N (N=3 here). But in this case the mean ± SD would only be 21.6 ± 2.45 g, which is clearly too low. I think this should be a simple problem to analyze, but I have yet to find a clear description of the appropriate equations to use. If my question is not clear please let me know. Any insight would be very appreciated. rano, May 25, 2012 Phys.org - latest science and technology news stories on Phys.org •Game over? Computer beats human champ in ancient Chinese game •Simplifying solar cells with a new mix of materials •Imaged 'jets' reveal cerium's post-shock inner strength May 25, 2012 #2 viraltux rano said: ↑ I was wondering if someone could please help me understand a simple problem of error propagation going from multiple measurements with errors to an average incorporating these errors. I have looked on several error propagation webpages (e.g. UC physics or UMaryland physics) but have yet to find exactly what I am looking for. I think this should be a simple problem to analyze, but I have yet to find a clear description of the appropriate equations to use. I
or more quantities, each with their individual uncertainties, and then combine the information from these quantities in order to come up with a final result of our experiment. How can you state your answer for the combined result of these measurements and their uncertainties scientifically? The answer to this fairly common question depends on how the individual measurements are combined in the result. We will treat each case separately: Addition of measured quantities If you have measured values for the quantities X, Y, and Z, with uncertainties dX, dY, and dZ, and your final result, R, is the sum or difference of these quantities, then the uncertainty dR is: Here the upper equation is an approximation that can also serve as an upper bound for the error. Please note that the rule is the same for addition and subtraction of quantities. Example: Suppose we have measured the starting position as x1 = 9.3+-0.2 m and the finishing position as x2 = 14.4+-0.3 m. Then the displacement is: Dx = x2-x1 = 14.4 m - 9.3 m = 5.1 m and the error in the displacement is: (0.22 + 0.32)1/2 m = 0.36 m Multiplication of measured quantities In the same way as for sums and differences, we can also state the result for the case of multiplication and division: Again the upper line is an approximation and the lower line is the exact result for independent random uncertainties in the individual variables. And again please note that for the purpose of error calculation there is no difference between multiplication and division. Example: We have measured a displacement of x = 5.1+-0.4 m during a time of t = 0.4+-0.1 s. What is the average velocity and the error in the average velocity? v = x / t = 5.1 m / 0.4 s = 12.75 m/s and the uncertainty in the velocity is: dv = |v| [ (dx/x)2 + (dt/t)2 ]1/2 = 12.75 m/s [(0.4/5.1)2 + (0.1/0.4)2]1/2 = 3.34 m/s Multiplication with a constant What if you have measured the uncertainty in an observable X, and you need to multiply it with a constant that is known exactly? What is the error then? This is easy: just multiply the error in X with the absolute value of the constant, and this will give you the error in R: If you compare this to the above rule for multiplication of two quantities, you see that this is just the special case of that rule for the uncertainty in c, dc = 0. Example: If an object is realeased from rest and is in free fall, and if you measure the velocity of this object at some point to be v = - 3.8+-0.3 m/s, how long has it been in free fall? Answer: we can calculate the time as (g = 9.81 m/s2 is assumed to be known exactly) t = - v / g = 3.8 m/s / 9.81 m/s2 = 0