Propagation Of Error
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Analytical Chemistry Quantifying Nature Expand/collapse global location Propagation of Error Last updated 20:33, 14 May 2016 Save as PDF Share Share Share Tweet Share IntroductionDerivation of error propagation definition Exact FormulaDerivation of Arithmetic ExampleCaveats and WarningsDisadvantages of Propagation of Error ApproachTreatment of Covariance TermsReferencesContributors Propagation of Error (or Propagation of Uncertainty) is defined as the effects on a function by a variable's uncertainty. It is a calculus derived statistical calculation designed to combine uncertainties from multiple variables, in order to provide an accurate error propagation square root measurement of uncertainty. Introduction Every measurement has an air of uncertainty about it, and not all uncertainties are equal. Therefore, the ability to properly combine uncertainties from different measurements is crucial. Uncertainty in measurement comes about in a variety of ways: instrument variability, different observers, sample differences, time of day, etc. Typically, error is given by the standard deviation (\(\sigma_x\)) of a measurement. Anytime a calculation requires more than one variable to solve, propagation of error is necessary to properly determine the uncertainty. For example, lets say we are using a UV-Vis Spectrophotometer to determine the molar absorptivity of a molecule via Beer's Law: A = ε l c. Since at least two of the variables have an uncertainty based on the equipment used, a propagation of error formula must be applied to measure a more exact uncertainty of the molar absorptivity. This example will be continued below, after the derivation (see Example Calculation). Derivation of Exact Formul
or more quantities, each with their individual uncertainties, and then combine the information from these quantities in order to come up with a final result of our experiment. How can you state your answer for the combined result of these measurements and their uncertainties scientifically? The answer to this fairly common
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question depends on how the individual measurements are combined in the result. We will treat each error propagation inverse case separately: Addition of measured quantities If you have measured values for the quantities X, Y, and Z, with uncertainties dX, dY, and dZ, and
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your final result, R, is the sum or difference of these quantities, then the uncertainty dR is: Here the upper equation is an approximation that can also serve as an upper bound for the error. Please note that the http://chem.libretexts.org/Core/Analytical_Chemistry/Quantifying_Nature/Significant_Digits/Propagation_of_Error rule is the same for addition and subtraction of quantities. Example: Suppose we have measured the starting position as x1 = 9.3+-0.2 m and the finishing position as x2 = 14.4+-0.3 m. Then the displacement is: Dx = x2-x1 = 14.4 m - 9.3 m = 5.1 m and the error in the displacement is: (0.22 + 0.32)1/2 m = 0.36 m Multiplication of measured quantities In the same way as for sums and differences, we can also state the result for http://lectureonline.cl.msu.edu/~mmp/labs/error/e2.htm the case of multiplication and division: Again the upper line is an approximation and the lower line is the exact result for independent random uncertainties in the individual variables. And again please note that for the purpose of error calculation there is no difference between multiplication and division. Example: We have measured a displacement of x = 5.1+-0.4 m during a time of t = 0.4+-0.1 s. What is the average velocity and the error in the average velocity? v = x / t = 5.1 m / 0.4 s = 12.75 m/s and the uncertainty in the velocity is: dv = |v| [ (dx/x)2 + (dt/t)2 ]1/2 = 12.75 m/s [(0.4/5.1)2 + (0.1/0.4)2]1/2 = 3.34 m/s Multiplication with a constant What if you have measured the uncertainty in an observable X, and you need to multiply it with a constant that is known exactly? What is the error then? This is easy: just multiply the error in X with the absolute value of the constant, and this will give you the error in R: If you compare this to the above rule for multiplication of two quantities, you see that this is just the special case of that rule for the uncertainty in c, dc = 0. Example: If an object is realeased from rest and is in free fall, and if you measure the velocity of this object at some point to be v = - 3.8+-0.3 m/s, how
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