Percentage Error 3 Significant Figures
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just how much the measured value is likely to deviate from the unknown, true, value of the quantity. The calculate systematic error art of estimating these deviations should probably be called uncertainty analysis, but
Random Error Calculation
for historical reasons is referred to as error analysis. This document contains brief discussions about how errors are percent error significant figures reported, the kinds of errors that can occur, how to estimate random errors, and how to carry error estimates into calculated results. We are not, and will not be, concerned
Fractional Error Formula
with the “percent error” exercises common in high school, where the student is content with calculating the deviation from some allegedly authoritative number. Significant figures Whenever you make a measurement, the number of meaningful digits that you write down implies the error in the measurement. For example if you say that the length of an object is 0.428 m, you imply fractional error definition an uncertainty of about 0.001 m. To record this measurement as either 0.4 or 0.42819667 would imply that you only know it to 0.1 m in the first case or to 0.00000001 m in the second. You should only report as many significant figures as are consistent with the estimated error. The quantity 0.428 m is said to have three significant figures, that is, three digits that make sense in terms of the measurement. Notice that this has nothing to do with the "number of decimal places". The same measurement in centimeters would be 42.8 cm and still be a three significant figure number. The accepted convention is that only one uncertain digit is to be reported for a measurement. In the example if the estimated error is 0.02 m you would report a result of 0.43 ± 0.02 m, not 0.428 ± 0.02 m. Students frequently are confused about when to count a zero as a significant figure. The rule is: If the zero has a non-zero digit anywhere to its left, then the zero is significant, otherwise it i
data book or other literature. If the 'correct' result is available it should be recorded and the percentage error calculated and commented upon in your conclusion. Without the 'correct ' value no useful comment on the error can be made. The percentage error is equal to: the difference between the
Fractional Error Physics
value obtained and the literature value x 100
Systematic Error Calculator
the literature value Uncertainty occurs due to the limitations of the apparatus itself and the taking of readings from how to calculate systematic error in physics scientific apparatus. For example during a titration there are generally four separate pieces of apparatus, each of which contributes to the uncertainty. When making a single measurement with a piece of apparatus then the absolute uncertainty and the percentage uncertainty can both http://www.owlnet.rice.edu/~labgroup/pdf/Error_analysis.htm be stated relatively easily. For example consider measuring 25.0 cm3 with a 25 cm3 pipette which measures to + 0.1 cm3. The absolute uncertainty is 0.1 cm3 and the percentage uncertainty is equal to: 0.1 x 100 = 0.4% 25.0 If two volumes or two masses are simply added or subtracted then the absolute uncertainties are added. For example suppose two volumes of 25.0 cm3 + 0.1 cm3 are added. In one extreme case the first volume could be 24.9 cm3 and the http://tasisibchem.blogspot.com/2011/09/error-and-uncertainty.html second volume 24.9 cm3 which would give a total volume of 48.8 cm3. Alternatively the first volume might have been 25.1 cm3 which when added to a second volume of 25.1 cm3 gives a total volume of 50.2 cm3. The final answer therefore can be quoted between 48.8 cm3 and 50.2 cm3, that is, 50.0 cm3 + 0.2 cm3. When using multiplication, division or powers then percentage uncertainties should be used during the calculation and then converted back into an absolute uncertainty when the final result is presented. For example, during a titration there are generally four separate pieces of apparatus, each of which contributes to the uncertainty. e.g. when using a balance that weighs to + 0.001 g the uncertainty in weighing 2.500 g will equal 0.001 x 100 = 0.04% 2.500 Similarly a pipette measures 25.00 cm3 + 0.04 cm3. The uncertainty due to the pipette is thus 0.04 x 100 = 0.16% 25.00 Assuming the uncertainty due to the burette and the volumetric flask is 0.50% and 0.10% respectively the overall uncertainty is obtained by summing all the individual uncertainties: Overall uncertainty = 0.04 + 0.16 + 0.50 + 0.10 = 0.80% ~ 1.0% Hence if the answer is 1.87 mol dm-3 the uncertainty is 1.0% or 0.0187 mol dm-3 The answer should be given as 1.87 + 0.02 mol dm-3. If the generally accepted ‘correct' value (obtained from the data book or other literature) is known then the total error in the result is
by 10 cm depends on whether you are measuring the length of a piece of paper or the distance from New Orleans to Houston. To express the magnitude of the error (or deviation) between http://archive.jesuitnola.org/upload/clark/labs/PerError.htm two measurements scientists invariably use percent error . If you are comparing your value to an accepted value, you first subtract the two values so that the difference you get is a positive number. This is called taking the absolute value of the difference. Then you divide this result (the difference) by the accepted value to get a fraction, and then multiply by 100% to get the percent error. systematic error So, % error = | your result - accepted value | x 100 % accepted value Several points should be noted when using this equation to obtain a percent error. 1) When you subtract note how many significant figures remain after the subtraction, and express your final answer to no more than that number of digits. 2) If neither of the two values being compared is an "accepted value", calculate systematic error then use either number in the denominator to get the fraction. If one value is more reliable than the other, choose it for the denominator. 3) Treat the % symbol as a unit. The fraction is dimensionless because units in the values will cancel. 4) Notice that the error is a positive number if the experimental value is too high, and is a negative number if the experimental value is too low. Example: A student measures the volume of a 2.50 liter container to be 2.38 liters. What is the percent error in the student's measurement? Ans. % error = (2.50 liters - 2.38 liters) x 100% 2.50 liters = (.12 liters) x 100% 2.50 liters = .048 x 100% = 4.8% error (Note only two sig figs left in the answer after the subtraction) Precision Frequently in science, an accepted or true value is not known. The accuracy of a measurement cannot be reported if an accepted value is unavailable. Precision is a measure of how reproducible experimental measurements are. Precision is reported as Deviation or Difference of values. The Absolute Deviation, or Absolute Difference, of each measurement is the difference of each measurement from the mean o